다분자층 흡착과 BET 흡착식의 통계 역학적 고찰

• 영문명: A Statistical-Mechanical Study on Multilayer Adsorptions and the BET Adsorption Equation
• 발행기관: 한국응용과학기술학회 (구.한국유화학회)
• 저자명: 임경희(Lim KyungHee)
• 간행물 정보: 『한국응용과학기술학회지』한국유화학회지 제23권 제4호, 280~289쪽, 전체 10쪽
• 주제분류: 공학 > 화학공학
• 파일형태: PDF
• 발행일자: 2006.12.31

영문 초록

Multilayer adsorptions and BET adsorption are analyzed statistical-mechanically. Which ensemble is selected for the analysis is unimportant, because each ensemble yields the same results. However, the amount of mathematical manipulations and the matter of convenience vary from ensemble to ensemble. Hence, multilayer adsorptions and BET adsorption are examined using a canonical and a grand canonical ensembles, and an ensemble of subsystems. Also, the characteristics of multilayer and BET adsorptions are delineated.

키워드

adsorption BET adsorption equation statistical mechanics multilayer adsorption ensemble