하이솔리드 아크릴수지의 합성 및 멜라민과의 경화속도 연구

• 영문명: Synthesis of High-Solids Acrylic Resins and Their Curing Rates with Melamine
• 발행기관: 한국응용과학기술학회 (구.한국유화학회)
• 저자명: 김승진(Seung Jin Kim) 김대원(Dae Won Kim) 임완빈(Wan Bin Im) 함현식(Hyun Sik Hahm) 박홍수(Hong Soo Park)
• 간행물 정보: 『한국응용과학기술학회지』한국유화학회지 제18권 제1호, 29~39쪽, 전체 11쪽
• 주제분류: 공학 > 화학공학
• 파일형태: PDF
• 발행일자: 2001.03.30

영문 초록

An acrylic resin was synthesized with several monomers, styrene(St), 2-hydroxyethyl methacrylate(2-HEMA), n-butyl acrylate, methyl methacrylate, and acetoacetoxyethl methacrylate(AAEM) to prepare a high-solid coatings. Then, a high-solid acryl/melamine coatings was prepared by curing the acrylic resin with a curing agent, hexamethoxymethylmelamine(HMMM). The curing behavior of the acrylic resin with HMMM was investigated by the Ozawa method using DSC. For AAEM/HMMM and 2-HEMA/HMMM curing reactions, activation energies were 33.01 and 27.12 kcal/mol and frequency factors were 9.54×10¹⁵ and 1.53×10¹³ min⁻¹, respectively. From the results, it was found out that 2-HEMA showed higher reactivity with the curing agent than AAEM.

목차

Abstract

1. 서론

2. 실험

3. 결과 및 고찰

4. 결론

김사의 글

참고문헌

키워드

high-solid activation energy frequency factor