Ga(III)-, In(III)-, TI(III)-porphyrin 유도체를 촉매제로 한 고리성 올레핀의 산화반응

• 영문명: Cycloolefins Oxidation Reaction Catalyzed by Ga(III)-, In(III)- and TI(III)-Porphyrin Derivatives
• 발행기관: 한국응용과학기술학회 (구.한국유화학회)
• 저자명: 나훈길(Na HunGil)
• 간행물 정보: 『한국응용과학기술학회지』한국유화학회지 제21권 제1호, 76~88쪽, 전체 13쪽
• 주제분류: 공학 > 화학공학
• 파일형태: PDF
• 발행일자: 2004.03.31

영문 초록

The catalytic oxidation reaction of several cycloolefins in CH2Cl2 have been investigated using non-redox metalloporphyrin(M = Ga(III), In(III) and TI(III) complexes as a catalyst and sodium hypochlorite as a terminal oxidant. Porphyrins were (p-CH3O)TPP, (p-CH_3)TPP, TPP, (p-F)TPP, (p-Cl)TPP and (F{20})TPP (TPP=5,10,15,20-tetraphenyl-21H,23H-porphyrin) and olefins were cyclopentene, cyclohexene, cycloheptene and cyclooctene, The substrate conversion yield(%) was investigated according to the radius effect of non-redox metal ion, substituent effect and hindrance effect of metalloporphyrin. The conversion yield of cycloolefin was in the following order : C5 < C6 < C7 =C8.

키워드

Ga(III)- In(III)- TI(III)-porphyrin cycloolefin oxidation