Vinyl 치환기를 갖는 4급탄소 Unit의 합성

• 영문명: Synthesis of Quaternary Carbon Unit Containing Vinyl Substituent.
• 발행기관: 대한약학회
• 저자명: 서영거(Young Ger Suh) 김화순(Hwa Soon Kim) 조윤상(Yoon Sang Cho)
• 간행물 정보: 『약학회지』제33권 제4호 (1989년), 226~228쪽, 전체 3쪽
• 주제분류: 의약학 > 기타의약학
• 파일형태: PDF
• 발행일자: 1989.08.25

영문 초록

In connection with the synthesis of the biologically active pimarane diterpenoids, some synthetic routes to the quaternary carbon unit were examined. Especially, Claisen rearrangement of allyl acetates prepared from acetol provided gamma-hydroxy acid containing vinyl substituent as the desired unit.

키워드

Claisen rearrangement gamma-hydroxy acid pimarane diterpenoid quaternary carbon