난연도료용 트리포스포러스 함유 변성폴리에스테르의 합성

• 영문명: Synthesis of Modified Polyesters Containing Triphosphorus for Flame-Retardant Coatings )
• 발행기관: 한국응용과학기술학회 (구.한국유화학회)
• 저자명: 박홍수(Park HongSoo) 유규열(Yoo GyuYeol) 김지현(Kim JiHyun) 김영근(Kim YoungGeun )
• 간행물 정보: 『한국응용과학기술학회지』한국유화학회지 제24권 제3호, 287~295쪽, 전체 9쪽
• 주제분류: 공학 > 화학공학
• 파일형태: PDF
• 발행일자: 2007.09.30

영문 초록

Three phosphorus functional groups were introduced in one structural unit of polymer backbone to enhance the flame retardancy of PU coatings. In the first step, we synthesized tetramethylene bis(orthophosphate) (TBOP) that contained two phosphorus functional groups in one structural unit. In the next step, we synthesized modified polyesters (ATBTP-10C, -20C, -30C) that contained triphosphorus group using TBOP, 1,4-butanediol, trimethylolpropane, adipic acid, and another functional monomer, phenylphosphonic acid (PPA). The amount of PPA in ATBTPs was adjusted from 10 wt% to 30 wt%. The structure and characteristics of ATBTPs were examined using FT-IR, NMR, GPC, and TGA analysis. From the thermo-behavior test of diphosphorus modified polyester (ATBT) and ATBTPs, the afterglow of ATBT, ATBTP-10C, ATBTP-20C, and ATBTP-30C were 24.7, 27.1, 29.0, and 31.7%, respectively. It was found from this result that the afterglow increased with the amount of PPA component.