Green Solvents in Organic Synthesis

Xiao-Feng Wu , Zhiping Yin , Liang-nian He , Feng Wang 지음

Wiley-VCH 2024년 03월 07일 출간

작품소개

책소개

Green Solvents in Organic Synthesis Essential reference on replacing conventional solvents with greener alternatives in industrial chemicals synthesis and production A well-timed book promoting sustainability in synthesis and production of chemicals, Green Solvents in Organic Synthesis details various green solvents, solvent systems, and solubilization techniques, including their chemistry, physiochemical properties, performance, and distinct applications, presenting a greener approach to conventional solvents by replacing them with sustainable alternatives that have similarities in their reaction mechanisms. Edited by four highly qualified academics with significant research experience in the field, Green Solvents in Organic Synthesis includes information on: Water and liquid polymers (Polyethylene glycol PEG), Acetonitrile, DMSO, Dimethyl carbonate, Ionic liquids, and Supercritical fluids)Bio-based solvents (Cyrene, γ-Valerolactone (GVL), Lactic acid, 2-MeTHF) and deep eutectic solvents (DESs)Alcohols (MeOH, EtOH, i-PrOH, n-BuOH, t-BuOH, Ethylene glycol), ketones (Acetones, MEK, MIBK, Cyclohexanone), and esters (Methyl acetate, Ethyl acetate, i-PrOAc, n-BuOAc)Technical, economic, and environmental aspects of green solvents and how to maximize their reuse and recycling to alleviate pollution and reduce energy consumption For chemists in a variety of disciplines, Green Solvents in Organic Synthesis is an essential reference that provides foundational knowledge of green solvents, along with key features of each class of green solvent within the context of organic reactions for industrial and laboratory synthesis.

목차

1 Recent Achievements in Organic Reactions in Alcohols 1 Lan Zhao, Man Zhao, Meng-Ge Wei, Hong-Ru Li, and Liang-Nian He 1.1 Introduction 1 1.2 Alcohols as Green Solvents 6 1.2.1 Hydrogenation/Reduction Reaction 6 1.2.2 Oxidation Reaction 8 1.2.3 Substitution Reaction 10 1.2.4 Addition Reaction 11 1.2.5 Cyclization Reaction 13 1.2.6 Coupling Reaction 18 1.2.7 Condensation/Ring Condensation Reaction 21 1.3 Alcohols as Green Solvents and Catalysts 28 1.3.1 Addition Reaction 28 1.3.2 Cyclization Reaction 28 1.3.3 Coupling Reaction 30 1.3.4 Condensation Reaction 30 1.3.5 Metathesis Reaction 35 1.4 Alcohols as Green Solvents and Hydrogen Donors 35 1.5 Miscellaneous 39 1.5.1 Polyethylene Glycol as a Solvent for CO 2 Capture and Conversion 39 1.5.2 Polyethylene Glycol Radical-Initiated Oxidation Reactions in Compressed Carbon Dioxide 41 1.5.3 Ring-Opening Reaction 43 1.6 Summary and Concluding Remarks 45 Acknowledgments 46 References 46 2 Recent Achievements in Organic Reactions in MeCN 51 Tongtong Xing, Guizhi Zhai, Linna Wu, Xiaofen Wang, and Zechao Wang 2.1 Introduction 51 2.2 MeCN in Transition Metal-catalyzed Reactions Without Radicals Involved 52 2.2.1 Transition Metal-catalyzed Addition Reactions in MeCN 52 2.2.2 Transition Metal-catalyzed Oxidation Reactions in MeCN 56 2.2.3 Transition Metal-catalyzed Reduction Reactions in MeCN 64 2.2.4 Transition Metal-catalyzed Substitution Reactions in MeCN 66 2.2.5 Transition Metal-catalyzed Cyclization Reactions in MeCN 74 2.3 MeCN in Transition Metal-free Catalyzed Reactions Without Radicals Involved 80 2.3.1 Transition Metal-free Catalyzed Cyclization Reactions in MeCN 80 2.3.2 Transition Metal-free Catalyzed Multicomponent Reactions in MeCN 84

출판사 서평

작가정보

저자(글) Xiao-Feng Wu

저자(글) Zhiping Yin

저자(글) Liang-nian He

저자(글) Feng Wang