Aromaticity and Antiaromaticity

Miquel Solà , Alexander I. Boldyrev , Michal K. Cyrañski , Tadeusz M. Krygowski , Gabriel Merino 지음

Wiley 2022년 10월 12일 출간

작품소개

책소개

Aromaticity and Antiaromaticity A comprehensive review of the science of aromaticity, as well as its evolution, from benzene to atomic clusters In Aromaticity and Antiaromaticity: Concepts and Applications, a team of accomplished chemists delivers a comprehensive exploration of the evolution and critical aspects of aromaticity. The book examines the new global criteria used to evaluate aromaticity, including the Nucleus Independent Chemical Shift (NICS) index and the electronic indices based on electronic properties. Additional discussions of inorganic aromatic compounds developed in this century, which give rise to new concepts like multifold aromaticity, are included. Three-dimensional aromaticity found in fullerenes and nanotubes, M bius aromaticity present in some annulenes, and excited state aromaticity are explored as well. This volume explores the geometrical, electronic, magnetic, and thermodynamic characteristics of aromatic and antiaromatic compounds and their reactivity properties. It also provides: A thorough historical overview of aromaticity, as well as simple electronic and structural models Comprehensive explorations of organic and inorganic aromatic compounds, concepts of stability and reactivity, and geometric, energetic, magnetic, and electronic criteria of descriptors of aromaticity Practical discussions of heteroaromaticity, as well as M bius aromaticity and excited state aromaticity In-depth examinations of sigma, pi, delta, and phi aromaticity Perfect for graduate students, researchers, and academics interested in aromaticity, organometallic chemistry, and computational chemistry, Aromaticity and Antiaromaticity: Concepts and Applications will also earn a place in the libraries of professionals and researchers working in organic, inorganic, and physical chemistry.

목차

Tentative table of contents: 1) Historical overview 2) Simple electronic and structural models (counting rules) 3) From Organic to Inorganic Aromatic Compounds 4) Stability, Reactivity, and Aromaticity 5) Descriptors of aromaticity: Geometric Criteria 6) Descriptors of aromaticity: Energetic Criteria 7) Descriptors of aromaticity: Magnetic Criteria 8) Descriptors of aromaticity: Electronic Criteria 9) Homoaromaticity 10) Heteroaromaticity 11) Möbius Aromaticity 12) Sigma, pi, delta, and phi Aromaticity 13) Distortivity of pi-electrons 14) Fullerenes and 3D-Aromaticity 15) Excited state aromaticity

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작가정보

저자(글) Miquel Solà

저자(글) Alexander I. Boldyrev

저자(글) Michal K. Cyrañski

저자(글) Tadeusz M. Krygowski

저자(글) Gabriel Merino