Physics and Chemistry of Interfaces

Hans-J?rgen Butt , Karlheinz Graf , Michael Kappl 지음

Wiley-VCH 2023년 01월 26일 출간

작품소개

책소개

Comprehensive textbook on the interdisciplinary field of interface science, fully updated with new content on spectroscopy, nonlinear effects, and coatings Physics and Chemistry of Interfaces provides a comprehensive introduction to the field of surface and interface science, focusing on essential concepts rather than specific details, and on intuitive understanding rather than convoluted math. Numerous high-end applications from surface technology, biotechnology, and microelectronics are included to illustrate and help readers easily comprehend basic concepts. The new edition contains an increased number of problems with detailed, worked solutions, making it ideal as a self-study resource. In topic coverage, the highly qualified authors take a balanced approach, discussing advanced interface phenomena in detail while remaining comprehensible. Chapter summaries with the most important equations, facts, and phenomena are included to aid the reader in information retention. A few of the sample topics included in Physics and Chemistry of Interfaces are as follows: Liquid surfaces, covering microscopic picture of a liquid surface, surface tension, the equation of Young and Laplace, and curved liquid surfaces Thermodynamics of interfaces, covering surface excess, internal energy and Helmholtz energy, equilibrium conditions, and interfacial excess energies Charged interfaces and the electric double layer, covering planar surfaces, the Grahame equation, and limitations of the Poisson-Boltzmann theory Surface forces, covering Van der Waals forces between molecules, macroscopic calculations, the Derjaguin approximation, and disjoining pressurePhysics and Chemistry of Interfaces is a complete reference on the subject, aimed at advanced students (and their instructors) in physics, material science, chemistry, and engineering. Researchers requiring background knowledge on surface and interf

목차

1. Introduction 2. Liquid Surfaces 2.1 Microscopic Picture of a Liquid Surface 2.2 Surface Tension 2.3 Equation of Young and Laplace 2.3.1 Curved Liquid Surfaces 2.3.2 Derivation of Young?Laplace Equation 2.3.3 Applying the Young?Laplace Equation 2.4 Techniques to Measure Surface Tension 2.5 Kelvin Equation 2.6 Capillary Condensation 2.7 Nucleation Theory 2.8 Summary 2.9 Exercises 3. Thermodynamics of Interfaces 3.1 Thermodynamic Functions for Bulk Systems 3.2 Surface Excess 3.3 Thermodynamic Relations for Systems with an Interface 3.3.1 Internal Energy and Helmholtz Energy 3.3.2 Equilibrium Conditions 3.3.3 Location of Interface 3.3.4 Gibbs Energy and Enthalpy 3.3.5 Interfacial Excess Energies 3.4 Pure Liquids 3.5 Gibbs Adsorption Isotherm 3.5.1 Derivation 3.5.2 System of Two Components 3.5.3 Experimental Aspects 3.5.4 Marangoni Effect 3.6 Summary 3.7 Exercises 4. Charged Interfaces and the Electric Double Layer 4.1 Introduction 4.2 Poisson?Boltzmann Theory of Diffuse Double Layer 4.2.1 Poisson?Boltzmann Equation 4.2.2 Planar Surfaces 4.2.3 The Full One-Dimensional Case 4.2.4 The Electric Double Layer around a Sphere 4.2.5 Grahame Equation 4.2.6 Capacitance of Diffuse Electric Double Layer 4.3 Beyond Poisson?Boltzmann Theory 4.3.1 Limitations of Poisson?Boltzmann Theory 4.3.2 Stern Layer 4.4 Gibbs Energy of Electric Double Layer 4.5 Electrocapillarity 4.5.1 Theory 4.5.2 Measurement of Electrocapillarity 4.6 Examples of Charged Surfaces 4.7 Measuring Surface Charge Densities 4.7.1 Potentiometric Colloid Titration 4.7.2 Capacitances 4.8 Electrokinetic Phenomena: the Zeta Potential 4.8.1 Navier?Stokes Equation 4.8.2 Electro-Osmosis and Streaming Potential 4.8.3 Electrophoresis and Sedimentation Potential 4.9 Types of Potential 4.10 Summary 4.11

출판사 서평

작가정보

저자(글) Hans-J?rgen Butt

저자(글) Karlheinz Graf

저자(글) Michael Kappl