Solid Oxide Fuel Cells

Bin Zhu , Rizwan Raza , Liangdong Fan , Chunwen Sun 지음

Wiley-VCH 2020년 02월 12일 출간

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Presents innovative approaches towards affordable, highly efficient, and reliable sustainable energy systems Written by leading experts on the subject, this book provides not only a basic introduction and understanding of conventional fuel cell principle, but also an updated view of the most recent developments in this field. It focuses on the new energy conversion technologies based on both electrolyte and electrolyte-free fuel cells?from advanced novel ceria-based composite electrolyte low temperature solid oxide fuel cells to non-electrolyte fuel cells as advanced fuel-to-electricity conversion technology. Solid Oxide Fuel Cells: From Electrolyte-Based to Electrolyte-Free Devices is divided into three parts. Part I covers the latest developments of anode, electrolyte, and cathode materials as well as the SOFC technologies. Part II discusses the non-electrolyte or semiconductor-based membrane fuel cells. Part III focuses on engineering efforts on materials, technology, devices and stack developments, and looks at various applications and new opportunities of SOFC using both the electrolyte and non-electrolyte principles, including integrated fuel cell systems with electrolysis, solar energy, and more. -Offers knowledge on how to realize highly efficient fuel cells with novel device structures -Shows the opportunity to transform the future fuel cell markets and the possibility to commercialize fuel cells in an extended range of applications -Presents a unique collection of contributions on the development of solid oxide fuel cells from electrolyte based to non-electrolyte-based technology -Provides a more comprehensive understanding of the advances in fuel cells and bridges the knowledge from traditional SOFC to the new concept -Allows readers to track the development from the conventional SOFC to the non-electrolyte or single-component fuel cell Solid Oxide Fuel Cells: From Electrolyte-Based to Electrolyt

목차

Preface xiii Part I Solid Oxide Fuel Cell with Ionic Conducting Electrolyte 1 1 Introduction 3Bin Zhu and Peter D. Lund 1.1 An Introduction to the Principles of Fuel Cells 3 1.2 Materials and Technologies 5 1.3 New Electrolyte Developments on LTSOFC 10 1.4 Beyond the State of the Art: The Electrolyte-Free Fuel Cell (EFFC) 20 1.4.1 Fundamental Issues 23 1.5 Beyond the SOFC 25 References 28 2 Solid-State Electrolytes for SOFC 35Liangdong Fan 2.1 Introduction 35 2.2 Single-Phase SOFC Electrolytes 37 2.2.1 Oxygen Ionic Conducting Electrolyte 37 2.2.1.1 Stabilized Zirconia 37 2.2.1.2 Doped Ceria 39 2.2.1.3 SrO- and MgO-Doped Lanthanum Gallates (LSGM) 42 2.2.2 Proton-Conducting Electrolyte and Mixed Ionic Conducting Electrolyte 42 2.2.3 Alternative New Electrolytes and Research Interests 44 2.3 Ion Conduction/Transportation in Electrolytes 49 2.4 Composite Electrolytes 52 2.4.1 Oxide Oxide Electrolyte 52 2.4.2 Oxide Carbonate Composite 53 2.4.2.1 Materials Fabrication 54 2.4.2.2 Performance and Stability Optimization 57 2.4.3 Other Oxide Salt Composite Electrolytes 60 2.4.4 Ionic Conduction Mechanism Studies of Ceria Carbonate Composite 62 2.5 NANOCOFC and Material Design Principle 66 2.6 Concluding Remarks 67 Acknowledgments 69 References 69 3 Cathodes for Solid Oxide Fuel Cell 79Tianmin He, Qingjun Zhou, and Fangjun Jin 3.1 Introduction 79 3.2 Overview of Cathode Reaction Mechanism 80 3.3 Development of Cathode Materials 82 3.3.1 Perovskite Cathode Materials 82 3.3.1.1 Mn-Based Perovskite Cathodes 83 3.3.1.2 Co-Based Perovskite Cathodes 85 3.3.1.3 Fe-Based Perovskite Cathodes 88 3.3.1.4 Ni-Based Perovskite

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저자(글) Bin Zhu

Bin Zhu, PhD, moved from KTH, Sweden as a Chief Scientist (Professor Director) of Energy Storage Joint Research Center, Southeast University, China. He has published more than 300 scientifc papers in nano-composite ionic conductors and new semiconductor-ionic materials for advanced fuel cells. Rizwan Raza, PhD, is Assistant Professor in the Department of Physics in COMSATS Institute of Information Technology, Pakistan. He has published more than 100 scientific papers. Liangdong Fan, PhD, is Lecturer in the College of Chemistry and Environmental Engineering at Shenzhen University, China. His interests focus on novel nanocomposite functional materials for fuel cells and electro-catalysis. Chunwen Sun is a Professor at Beijing Institute of Nanoenergy and Nanosystems (BINN), Chinese Academy of Sciences (CAS). His research interests include energy storage and conversion, e.g., lithium/sodium-ion batteries, metal-air batteries, all-solid-state batteries, fuel cells and self-power systems.

저자(글) Rizwan Raza

저자(글) Liangdong Fan

저자(글) Chunwen Sun