Hydrogen Bonding in Polymeric Materials

Shiao-Wei Kuo 지음

Wiley-VCH 2018년 01월 18일 출간

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책소개

Summarizing our current knowledge of the topic, this book describes the roles and effects of hydrogen bonding in polymer materials by reviewing the latest developments over recent years. To this end, it discusses all relevant aspects from the fundamentals, via characterization, to properties and applications in various polymeric materials, including polymer blends, block copolymers, mesoporous materials, biomacromolecules and nanocomposites. Invaluable reading for scientists in polymers and materials as well as those working in macromolecular chemistry.

목차

Preface ix Abbreviation xi 1 Hydrogen Bonding in Polymeric Materials 1 1.1 Introduction 1 1.1.1 Hydrogen Bonds 2 1.1.2 Characterization of Hydrogen Bonding 3 References 6 2 Hydrogen Bonding in Polymer Blends 9 2.1 Thermodynamic Properties of Polymer Blends 10 2.2 Association Model Approach 12 2.3 Measurement of Hydrogen Bonding Using Infrared Spectroscopy 14 2.3.1 Self-Association Equilibrium Constants 14 2.3.2 Interassociation Equilibrium Constants 17 2.4 Factors Influencing Hydrogen Bonds 20 2.4.1 Intramolecular Screening Effect 21 2.4.2 Functional Group Accessibility 21 2.4.3 Acidity of H-Bond Donor Groups 23 2.4.4 Basicity of H-Bond Acceptor Groups 24 2.4.5 Steric Hindrance 25 2.4.6 Bulky Group Effect 25 2.4.7 Temperature Effect 26 2.4.8 Solvent Effect 28 2.5 Miscibility EnhancementThrough Hydrogen Bonding 28 2.5.1 Miscibility Characterization 28 2.5.2 Incorporation of H-Bonding Functional Groups in Polymer Chains 30 2.5.3 Effect of Inert Diluent Segment 32 2.5.4 Ternary Polymer Blends 33 References 36 3 Physical Properties of Hydrogen-Bonded Polymers 41 3.1 Glass Transition Temperatures 41 3.1.1 Positive Deviation of Glass Transition Temperature 41 3.1.2 Negative Deviation of Glass Transition Temperature 48 3.2 Melting Temperature (Tm) 50 3.3 Dynamic Behavior 51 3.4 Crystallization Behavior 54 References 56 4 Surface Properties of Hydrogen-Bonded Polymers 61 4.1 Low Surface Energy Polymers 61 4.1.1 Polybenzoxazines 63 4.1.2 Poly(vinyl phenol) 67 4.1.3 Antisticking Applications of PBZs 72 4.1.4 Tuning the Surface Properties of PBZ Thin Films 73 4.2 Superhydrophobic Surfaces 78 4.2.1 Superhydrophobic Surfaces of PBZ after Plasma Treatmen

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저자(글) Shiao-Wei Kuo

Shiao-Wei Kuo is Professor in the Department of Materials and Optoelectronic Science at National Sun Yat-Sen University, Taiwan. He received his PhD in Applied Chemistry from National Chiao-Tung University, Taiwan. After some years of postdoctoral research work there and in the University of Akron, USA, he joined National Sun Yat-Sen University as a faculty member. His research interests include polymers, supramolecules, self-assembly nanostructures, mesoporous materials, POSS nanocomposites, low surface free energy materials, and polypeptides. He has published over 240 research papers and several book chapters.