Ruthenium Complexes

Alvin A. Holder , Lothar Lilge , Wesley R. Browne , Mark A.W. Lawrence , Jimmie L. Bullock , Jr. 지음

Wiley-VCH 2017년 10월 27일 출간

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책소개

Edited by a team of highly respected researchers combining their expertise in chemistry, physics, and medicine, this book focuses on the use of ruthenium-containing complexes in artificial photosynthesis and medicine. Following a brief introduction to the basic coordination chemistry of ruthenium-containing complexes and their synthesis, as well as their photophysical and photochemical properties, the authors discuss in detail the major concepts of artificial photosynthesis and mechanisms of hydrogen production and water oxidation with ruthenium. The second part of the text covers biological properties and important medical applications of ruthenium-containing complexes as therapeutic agents or in diagnostic imaging. Aimed at stimulating research in this active field, this is an invaluable information source for researchers in academia, health research institutes, and governmental departments working in the field of organometallic chemistry, green and sustainable chemistry as well as medicine/drug discovery, while equally serving as a useful reference also for scientists in industry.

목차

About the Editors xv Preface xvii Acknowledgments xix Section I Introduction 1 1 Karen J. Brewer (1961 2014): A Bright Star that Burned Out Far Too Soon 3Seth C. Rasmussen 1.1 Introduction 3 1.2 Early Years 4 1.3 Graduate Studies and Clemson University 6 1.4 Postdoctoral Research and the University of California, Berkeley 11 1.5 Washington State University: Beginning an Independent Career 13 1.6 Move to Virginia Tech 15 1.7 Collaboration with BrendaWinkel and the Study of Metal-DNA Interactions 16 1.8 A Return to Where It All Started: Photochemical H2 Production 18 1.9 A Career Cut Tragically Short 19 1.10 Karen’s Legacy 20 Acknowledgments 20 References 20 2 Basic Coordination Chemistry of Ruthenium 25Mark A.W. Lawrence, Jimmie L. Bullock, and Alvin A. Holder 2.1 Coordination Chemistry of Ruthenium 25 2.1.1 The Element 25 2.1.2 Stereochemistry and Common Oxidation States 26 2.1.2.1 Ruthenium in Low Oxidation States 27 2.1.2.2 Chemistry of Ruthenium(II) and (III) 31 2.1.2.3 Higher Oxidation States of Ruthenium 36 2.1.3 Conclusion 37 References 37 Section II Artificial Photosynthesis 43 3 Water Oxidation Catalysis with Ruthenium 45Andrea Sartorel 3.1 Introduction 45 3.1.1 Energy Issue and Energy from the Sun 45 3.1.2 Photosynthesis and Solar Fuels 46 3.1.3 Water Oxidation 48 3.1.4 ArtificialWater Oxidation 49 3.2 Ruthenium inWater Oxidation Catalyst 50 3.2.1 Ruthenium Oxide 50 3.2.2 Molecular Ruthenium WOC 52 3.2.2.1 Meyer’s Blue Dimer 53 3.2.2.2 The Ru-Hbpp Catalyst 54 3.2.2.3 Single-Site Ru-WOCs 55 3.2.2.4 Heptacoordinated Ru Intermediates 56 3.2.3 Polyoxometalates: The Bridge Between Metal Oxides and Coord

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저자(글) Alvin A. Holder

Alvin A. Holder is an associate professor at Old Dominion University in Norfolk, U.S.A. He graduated from the University of the West Indies, Barbados, with a B.Sc. and acquired his Ph.D. in inorganic chemistry with Prof. Tara P. Dasgupta. He was a faculty member at the University of the West Indies, Cave Hill Campus, Barbados, and an assistant professor in chemistry at the University of Southern Mississippi. His current research involves transition metal chemistry and he has published more than 60 articles and several textbooks and book chapters. In 2012, he was awarded an NSF Career Award. Lothar Lilge is a senior scientist at the Princess Margaret Cancer Centre and holds a professorship at the University of Toronto, Canada. He obtained his Diploma in physics from the Johann Wolfgang Goethe University in Frankfurt, Germany, and his Ph.D. degree in biophysics from the Westfaehlische Wilhelms University in Muenster, Germany. Additional training was provided through the Wellman Laboratories of Photomedicine at Massachusetts General Hospital, Boston, U.S.A., and during a post-doc at McMaster University in Hamilton, Canada. His work is focused on photodynamic therapy including the use of ruthenium-based photosensitizers and optical spectroscopy for diagnostic and risk assessment among a range of other biophotonic application in medicine. Wesley R. Browne is an associate professor at Stratingh Institute for Chemistry at the University of Groningen, The Netherlands, since 2013. He completed his Ph.D. degree at Dublin City University, Ireland, with Prof. J. G. Vos in 2002, followed by a postdoc under the joint guidance of Prof. J. G. Vos and Prof. J. J. McGarvey, Queens University Belfast, U.K. Between 2003 and 2007 he was a postdoctoral research fellow in the group of Prof. B. L. Feringa at the University of Groningen. He was appointed assistant professor in 2008. His current research interests include transition metal based oxidation catalysis, electroc

저자(글) Lothar Lilge

저자(글) Wesley R. Browne

저자(글) Mark A.W. Lawrence

저자(글) Jimmie L. Bullock

저자(글) Jr.