Electrodeposition from Ionic Liquids

Frank Endres , Andrew Abbott , Douglas MacFarlane 지음

Wiley-VCH 2017년 02월 17일 출간

작품소개

책소개

Edited by distinguished experts in this expanding field and with specialist contributions, this overview is the first of its kind to focus on electrodeposition from ionic liquids. This second edition has been completely revised and updated with approximately 20% new content and has been expanded by five chapters to cover the following topics: -Bulk and Interface Theory -Nanoscale Imaging including AFM, In situ STM and UHV-STM -Impedance Spectroscopy -Process Scale-up including Brighteners -Speciation and Redox Properties. The result is essential reading for electrochemists, materials scientists, chemists in industry, physical chemists, chemical engineers, inorganic and organic chemists.

목차

List of Contributors xvii Abbreviations xxi 1 Why Use Ionic Liquids for Electrodeposition? 1Andrew P. Abbott, Frank Endres, and Douglas R. Macfarlane 1.1 Nonaqueous Solutions 2 1.2 Ionic Fluids 3 1.3 What Is an Ionic Liquid? 4 1.4 Technological Potential of Ionic Liquids 6 1.5 Conclusions 11 References 12 2 Synthesis of Ionic Liquids 17Tom Beyersdorff, Thomas J. S. Schubert, UrsWelz-Biermann,Will Pitner, Andrew P. Abbott, Katy J. McKenzie, and Karl S. Ryder 2.1 Nanostructured Metals and Alloys Deposited from Ionic Liquids 17Thomas J. S. Schubert References 24 2.2 Air- andWater-Stable Ionic Liquids 26Thomas J. S. Schubert References 35 2.3 Eutectic-Based Ionic Liquids 38Andrew P. Abbott References 50 3 Physical Properties of Ionic Liquids for Electrochemical Applications 55Hiroyuki Ohno 3.1 Introduction 55 3.2 Thermal Properties 55 3.3 Viscosity 62 3.4 Density 64 3.5 Refractive Index 65 3.6 Polarity 67 3.7 Solubility of Metal Salts 73 3.8 Electrochemical Properties 76 3.9 Conclusion and Future Prospects 86 Acknowledgments 86 References 86 4 Electrodeposition of Metals 954.1 Electrodeposition in AlCl3-Based Ionic Liquids 95Thomas Schubert References 103 4.2 Electrodeposition of Refractory Metals from Ionic Liquids 104Giridhar Pulletikurthi, Natalia Borisenko, and Frank Endres References 115 4.3 Deposition of Metals from Nonchloroaluminate Eutectic Mixtures 119Andrew P. Abbott and Karl S. Ryder References 131 4.4 Troublesome Aspects 132Andrew P. Abbott and Frank Endres References 137 4.5 Complexation and Redox Behavior ofMetal Ions in Ionic Liquids 137

인물정보

저자(글) Frank Endres

Frank Endres studied chemistry and physics at Saarland University, Germany, gaining his doctorate in 1996. He obtained his lecturing qualification at Karlsruhe University in 2002, since when he has been a full professor at Clausthal University of Technology. Andrew Abbott gained his PhD in electrochemistry from Southampton University in 1989. Following post-doctoral studies at the universities of Connecticut and Liverpool, he became a lecturer at the University of Leicester in 1993, and Professor of Physical Chemistry there in 2005. Since 1999, Professor Abbott has been Research Director of Scionix Ltd. Professor Doug MacFarlane leads the Monash Ionic Liquids Group at Monash University. He is currently the holder of an Australian Research Council Laureate Fellowship. He is also the Program Leader of the Energy Program in the Australian Centre of Excellence for Electromaterials Science. His group focuses on a range of aspects of ionic liquids and their application in the energy sciences and sustainable chemistry. Professor MacFarlane was a BSc(Hons) graduate of Victoria University of Wellington, New Zealand and then undertook his graduate work in the Angell group at Purdue University, Indiana, graduating in 1983. After postdoctoral fellowships in France and New Zealand he took up an academic position at Monash. He has been a Professor of Chemistry at Monash since 1995 and was Head of School 2003-2006.

저자(글) Andrew Abbott

저자(글) Douglas MacFarlane