Liquid-State Physical Chemistry

Gijsbertus de With 지음

Wiley-VCH 2013년 07월 15일 출간

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책소개

For many processes and applications in science and technology a basic knowledge of liquids and solutions is a must. Gaining a better understanding of the behavior and properties of pure liquids and solutions will help to improve many processes and to advance research in many different areas. This book provides a comprehensive, self-contained and integrated survey of this topic and is a must-have for many chemists, chemical engineers and material scientists, ranging from newcomers in the field to more experienced researchers. The authoroffers a clear, well-structured didactic approach and provides an overview of the most important types of liquids and solutions. Special topics include chemical reactions, surfaces and phase transitions. Suitable both for introductory as well as intermediate level as more advanced parts are clearly marked. Includes also problems and solutions.

목차

Preface XVAcknowledgments XIXList of Important Symbols and Abbreviations XXV1 Introduction 11.1 The Importance of Liquids 11.2 Solids, Gases, and Liquids 21.3 Outline and Approach 51.4 Notation 8References 9Further Reading 92 Basic Macroscopic and Microscopic Concepts: Thermodynamics, Classical, and Quantum Mechanics 112.1 Thermodynamics 112.2 Classical Mechanics 262.3 Quantum Concepts 352.4 Approximate Solutions 44References 51Further Reading 513 Basic Energetics: Intermolecular Interactions 533.1 Preliminaries 533.2 Electrostatic Interaction 553.3 Induction Interaction 593.4 Dispersion Interaction 603.5 The Total Interaction 633.6 Model Potentials 653.7 Refinements 683.8 The Virial Theorem 72References 72Further Reading 734 Describing Liquids: Phenomenological Behavior 754.1 Phase Behavior 754.2 Equations of State 764.3 Corresponding States 79References 86Further Reading 875 The Transition from Microscopic to Macroscopic: Statistical Thermodynamics 895.1 Statistical Thermodynamics 895.2 Perfect Gases 1015.3 The Semi-Classical Approximation 1045.4 A Few General Aspects 1105.5 Internal Contributions 1125.6 Real Gases 118References 126Further Reading 1276 Describing Liquids: Structure and Energetics 1296.1 The Structure of Solids 1296.2 The Meaning of Structure for Liquids 1326.3 The Experimental Determination of g(r) 1386.4 The Structure of Liquids 1406.5 Energetics 1466.6 The Potential of Mean Force 150References 154Further Reading 1547 Modeling the Structure of Liquids: The Integral Equation Approach 1557.1 The Vital Role of the Correlation Function

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저자(글) Gijsbertus de With

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Gijsbertus de With is full professor in materials science. He graduated from Utrecht State University and received his PhD in 1977 from theUniversity of Twente on the 'Structure and charge distribution of molecular crystals'. In the same year he joined Philips ResearchLaboratories, Eindhoven. In 1985 he was appointed part-time professor and in 1996 he became full professor at the Eindhoven Universityof Technology. Since 2006 he is also chairman of the Soft Matter CryoTEM Research Unit. His research interests cover structural andinterfacial phenomena in relation to the processing and behavior of multi-phase materials. He has (co)-authored more than 250 researchpapers and holds about 20 patents. He is a member of the Advisory board of the J. Eur. Ceram. Soc. and is presently co-organizer of theannual Coatings Science International conferences. In 2006 his twovolume monograph Structure, Deformation, and Integrity of Materialswas published.