Nanopatterned and Nanoparticle-Modified Electrodes

Richard C. Alkire , Philip N. Bartlett , Jacek Lipkowski 지음

Wiley-VCH 2017년 03월 13일 출간

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Volume XVII in the "Advances in Electrochemical Science and Engineering" series, this monograph covers progress in this rapidly developing field with a particular emphasis on important applications, including spectroscopy, medicinal chemistry and analytical chemistry. As such it covers nanopatterned and nanoparticle-modified electrodes for analytical detection, surface spectroscopy, electrocatalysis and a fundamental understanding of the relation between the electrode structure and its function. Written by a group of international experts, this is a valuable resource for researchers working in such fields as electrochemistry, materials science, spectroscopy, analytical and medicinal chemistry.

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List of Contributors XI Series Preface XVII Preface XIX 1 Surface Electrochemistry with Pt Single-Crystal Electrodes 1Victor Climent and Juan M. Feliu 1.1 Introduction 1 1.2 Concepts of Surface Crystallography 2 1.3 Preparation of Single-Crystal andWell-Oriented Surfaces 9 1.4 Understanding the Voltammetry of Platinum 13 1.4.1 CO Charge Displacement Experiment 15 1.4.2 Stepped Surfaces 18 1.5 Potential of Zero Charge of Platinum Single Crystals 24 1.5.1 Total Charge Curves in Coulometric Analysis 29 1.5.2 Model for the Estimation of the Potential of Zero Free Charge 32 1.5.3 Applications of Electrocapillary Equation 32 1.6 The Laser-Induced Temperature Jump Method and the Potential of Maximum Entropy 34 1.7 Electrocatalytic Studies with Single-Crystal Electrodes 40 1.7.1 Carbon Monoxide on Platinum 40 1.7.2 Oxygen Reduction 43 1.8 Concluding Remarks 47 Acknowledgments 49 References 49 2 Electrochemically Shape-Controlled Nanoparticles 59Lu Wei, Na Tian, Zhi Y. Zhou, and Shi G. Sun 2.1 Introduction 59 2.2 Metal Nanoparticles of High-Index Facets and High Surface Energy 60 2.2.1 NPs of {hk0} High-Index Facets 61 2.2.2 NPs of {hkk} High-Index Facets 66 2.2.3 NPs of {hhl} High-Index Facets 66 2.2.4 NPs of {hkl} High-Index Facets 69 2.2.5 Electrochemistry-Mediated Shape Evolution 71 2.2.6 Electrochemical Milling and Faceting 72 2.3 Metallic Alloy Nanoparticles of High-Index Facets and High Surface Energy 73 2.3.1 Pd Pt Alloy NPs 74 2.3.2 Pt Rh Alloy NPs 76 2.3.3 Fe Ni Alloy NPs 77 2.4 Metal Nanoparticles of Low-Index Facets 79 2.4.1 Fe NPs with High Surface Energy 79 2.4.2 Cu NPs 81 2.4.3 Pt NPs 83 2.5 Nanoparticles of Metal Oxides and Chalcogenides 84 2.5.1 Cu

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저자(글) Richard C. Alkire

Richard C. Alkire is Professor Emeritus of Chemical & Biomolecular Engineering Charles and Dorothy Prizer Chair at the University of Illinois, Urbana, USA. He obtained his degrees at Lafayette College and University of California at Berkeley. He has received numerous prizes, including Vittorio de Nora Award and Lifetime National Associate award from National Academy. Philip N. Bartlett is Head of the Electrochemistry Section, Deputy Head of Chemistry for Strategy, and Associate Dean for Enterprise in the Faculty of Natural and Environmental Sciences at the University of Southampton. He received his PhD from Imperial College London and was a Lecturer at the University of Warwick and a Professor for Physical Chemistry at the University of Bath, before moving to his current position. His research interests include bioelectrochemistry, nanostructured materials, and chemical sensors. Jacek Lipkowski is Professor at the Department of Chemistry and Biochemistry at the University of Guelph, Canada. His research interests focus on surface analysis and interfacial electrochemistry. He has authored over 120 publications and is a member of several societies, including a Fellow of the International Society of Electrochemistry.

저자(글) Philip N. Bartlett

저자(글) Jacek Lipkowski