Hydrogen Bonding and Transfer in the Excited State

Ke-Li Han 지음

Wiley 2011년 03월 16일 출간

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This book gives an extensive description of the state-of-the-art in research on excited-state hydrogen bonding and hydrogen transfer in recent years.Initial chapters present both the experimental and theoretical investigations on the excited-state hydrogen bonding structures and dynamics of many organic and biological chromophores. Following this, several chapters describe the influences of the excited-state hydrogen bonding on various photophysical processes and photochemical reactions, for example: hydrogen bonding effects on fluorescence emission behaviors and photoisomerization; the role of hydrogen bonding in photosynthetic water splitting; photoinduced electron transfer and solvation dynamics in room temperature ionic liquids; and hydrogen bonding barrier crossing dynamics at bio-mimicking surfaces. Finally, the book examines experimental and theoretical studies on the nature and control of excited-state hydrogen transfer in various systems.Hydrogen Bonding and Transfer in the Excited State is an essential overview of this increasingly important field of study, surveying the entire field over 2 volumes, 40 chapters and 1200 pages. It will find a place on the bookshelves of researchers in photochemistry, photobiology, photophysics, physical chemistry and chemical physics.

목차

Preface.List of Contributors.Volume I.1. Vibrational Dynamics of the Hydrogen Bonds in Nucleic Acid Base Pairs (Yun-An Yan and Oliver Kühn).1.1 Introduction.1.2 Hydrogen Bonding and Nonlinear Infrared Spectroscopy.1.3 Correlated Vibrational Dynamics of an Adenine-Uracil Derivative in Solution.1.4 Conclusion.References.2. Vibrational Energy Relaxation Dynamics of XH Stretching Vibrations of Aromatic Molecules in the Electronic Excited State (Takayuki Ebata).2.1 Introduction.2.2 IR Spectra of 2-Naphthol and Its H-Bonded Clusters in S1 State.2.3 VER Dynamics of Bare 2-Naphthol.2.4 VER Dynamics of H-Bonded Clusters of 2-Naphthol.2.5 Comparison of the Cis®Trans Barrier Height between S0 and S1.2.6 Conclusion.References.3. The Hydrogen-Bond Basicity in the Excited State. Concept and Applications (Attila Demeter).3.1 Introduction.3.2 Experiment.3.3 Result and Discussion.3.3.1 Absorption and Fluorescence Spectra of the Complexed Species.3.3.2 Hydrogen-Bond Basicity of the Ground and Singlet Excited State.3.3.3 Reaction Rate of Hydrogen-Bonded Complex Formation In Excited State.3.3.4 Solvatochromism of DMAP and Its Singly Complexed Derivative: Estimation of the Dipole Moment of A Singlet Excited Complexes.3.3.5 Triplet State Properties of the Complexed Species.3.4 Summary.Acknowledgement.References.4. Solute&~Solvent Hydrogen Bond Formation in the Excited State. Experimental and theoretical Evidences (Iulia Matei, Sorana Ionescu, Mihaela Hillebrand).4.1 Introduction.4.2 The Prerequisite Conditions for Hydrogen Bond Formation.4.3 Diagnosis Criteria and Quantitative Treatment of the Hydrogen Bonds.4.4 Design of the Experiments.4.5 Theoretical Modelling of the H Bonds.4.6 Conclusions.References.5. Electronic Excited State Structures and Properties of Hydrated Dna Bases and Base Pairs (

출판사 서평

"This book gives an extensive description of the state-of-the-art in research on excited-state hydrogen bonding and hydrogen transfer in recent years. Initial chapters present both the experimental and theoretical investigations on the excited-state hydrogen bonding structures and dynamics of many organic and biological chromophores." (ADVFN India, 22 November 2010)&

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저자(글) Ke-Li Han

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Ke-Li Han, State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China.Guang-Jiu Zhao, State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China.