Electrochemical Impedance Spectroscopy

Mark E. Orazem , Bernard Tribollet 지음

Wiley 2017년 04월 10일 출간

작품소개

책소개

Provides fundamentals needed to apply impedance spectroscopy to a broad range of applications with emphasis on obtaining physically meaningful insights from measurements. Emphasizes fundamentals applicable to a broad range of applications including corrosion, biomedical devices, semiconductors, batteries, fuel cells, coatings, analytical chemistry, electrocatalysis, materials, and sensors Provides illustrative examples throughout the text that show how the principles are applied to common impedance problems New Edition has improved pedagogy, with more than twice the number of examples New Edition has more in-depth treatment of background material needed to understand impedance spectroscopy, including electrochemistry, complex variables, and differential equations New Edition includes expanded treatment of the influence of mass transport and kinetics and reflects recent advances in understanding frequency dispersion and constant-phase elements

목차

Preface to the Second Edition xvii Preface to the First Edition xix Acknowledgments xxiii The Blind Men and the Elephant xxv A Brief Introduction to Impedance Spectroscopy xxix History of Impedance Spectroscopy xxxvii I Background 1 1 Complex Variables 3 1.1 Why Imaginary Numbers? 3 1.2 Terminology 4 1.3 Operations Involving Complex Variables 5 1.4 Elementary Functions of Complex Variables 16 Problems 22 2 Differential Equations 25 2.1 Linear First-Order Differential Equations 25 2.2 Homogeneous Linear Second-Order Differential Equations 29 2.3 Nonhomogeneous Linear Second-Order Differential Equations 32 2.4 Chain Rule for Coordinate Transformations 36 2.5 Partial Differential Equations by Similarity Transformations 38 2.6 Differential Equations with Complex Variables 42 Problems 43 3 Statistics 45 3.1 Definitions 45 3.2 Error Propagation 53 3.3 Hypothesis Tests 59 Problems 70 4 Electrical Circuits 73 4.1 Passive Electrical Circuits 73 4.2 Fundamental Relationships 79 4.3 Nested Circuits 80 4.4 Mathematical Equivalence of Circuits 82 4.5 Graphical Representation of Circuit Response 82 Problems 85 5 Electrochemistry 87 5.1 Resistors and Electrochemical Cells 87 5.2 Polarization Behavior for Electrochemical Systems 90 5.3 Definitions of Potential 106 5.4 Rate Expressions 107 5.5 Transport Processes 111 5.6 Potential Contributions 117 5.7 Capacitance Contributions 120 5.8 Further Reading 124 Problems 125 6 Electrochemical Instrumentation 127 6.1 The Ideal Operational Amplifier 127 6.2 Elements of Electrochemical Instrumentation 129 6.3 Electrochemical Interface 131 Problems 135 II Expe

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저자(글) Mark E. Orazem

Mark E. Orazem is a Distinguished Professor of Chemical Engineering at the University of Florida, adjunct professor at the Beijing University of Chemical Technology, a Fellow of the Electrochemical Society, past President of the International Society of Electrochemistry, and recipient of the 2012 ECS Linford Award for Outstanding Teaching. He organized the 6th International Symposium on Electrochemical Impedance Spectroscopy and teaches short courses on impedance spectroscopy for industry and for The Electrochemical Society. Bernard Tribollet is Director of Research Emeritus at the Laboratory for Interfaces and Electrochemical Systems (LISE) at the University of Pierre and Marie Curie and adjunct professor at the Beijing University of Chemical Technology. He instructs an annual short course at his university on impedance spectroscopy. He is a Fellow of The Electrochemical Society, Treasurer of the International Society of Electrochemistry, and organized the 2010 Annual Meeting of the International Society of Electrochemistry held in Nice, France.

저자(글) Bernard Tribollet