Introduction to Catalysis and Industrial Catalytic Processes

Robert J. Farrauto , Lucas Dorazio , C. H. Bartholomew 지음

Wiley-AIChE 2020년 03월 06일 출간

작품소개

책소개

Introduces major catalytic processes including products from the petroleum, chemical, environmental and alternative energy industries Provides an easy to read description of the fundamentals of catalysis and some of the major catalytic industrial processes used today Offers a rationale for process designs based on kinetics and thermodynamics Alternative energy topics include the hydrogen economy, fuels cells, bio catalytic (enzymes) production of ethanol fuel from corn and biodiesel from vegetable oils Problem sets of included with answers available to faculty who use the book Review:"In less than 300 pages, it serves as an excellent introduction to these subjects whether for advanced students or those seeking to learn more about these subjects on their own time...Particularly useful are the succinct summaries throughout the book...excellent detail in the table of contents, a detailed index, key references at the end of each chapter, and challenging classroom questions..." (GlobalCatalysis.com, May 2016)

목차

PREFACE XV ACKNOWLEDGMENTS XVII LIST OF FIGURES XIX NOMENCLATURE XXVII CHAPTER 1 CATALYST FUNDAMENTALS OF INDUSTRIAL CATALYSIS 1 1.1 Introduction 1 1.2 Catalyzed versus Noncatalyzed Reactions 1 1.3 Physical Structure of a Heterogeneous Catalyst 6 1.4 Adsorption and Kinetically Controlled Models for Heterogeneous Catalysis 10 1.5 Supported Catalysts: Dispersed Model 19 1.6 Selectivity 24 Questions 27 Bibliography 29 CHAPTER 2 THE PREPARATION OF CATALYTIC MATERIALS 31 2.1 Introduction 31 2.2 Carrier Materials 32 2.3 Incorporating the Active Material into the Carrier 37 2.4 Forming the Final Shape of the Catalyst 40 2.5 Catalyst Physical Structure and Its Relationship to Performance 45 2.6 Nomenclature for Dispersed Catalysts 45 Questions 46 Bibliography 46 CHAPTER 3 CATALYST CHARACTERIZATION 48 3.1 Introduction 48 3.2 Physical Properties of Catalysts 49 3.3 Chemical and Physical Morphology Structures of Catalytic Materials 54 3.4 Spectroscopy 65 Questions 66 Bibliography 67 CHAPTER 4 REACTION RATE IN CATALYTIC REACTORS 69 4.1 Introduction 69 4.2 Space Velocity, Space Time, and Residence Time 69 4.3 Definition of Reaction Rate 71 4.4 Rate of Surface Kinetics 72 4.5 Rate of Bulk Mass Transfer 78 4.6 Rate of Pore Diffusion 80 4.7 Apparent Activation Energy and the Rate-Limiting Process 82 4.8 Reactor Bed Pressure Drop 83 4.9 Summary 84 Questions 84 Bibliography 87 CHAPTER 5 CATALYST DEACTIVATION 88 5.1 Introduction 88 5.2 Thermally Induced Deactivation 88 5.3 Poisoning 96 5.4 Coke Formation and Catalyst Regeneration 99 Questions 101 Bibliography 103 CHAPTER 6 GENERATING HYDROGEN AND SYNTHESIS GAS BY C

출판사 서평

"In less than 300 pages it serves as an excellent introduction to these subjects whether for advanced students or those seeking to learn more about these subjects on their own time...Particularly useful are the succinct summaries throughout the book...excellent detail in the table of contents, a detailed index, key references at the end of each chapter, and challenging classroom questions..." (GlobalCatalysis.com, May 2016)

작가정보

저자(글) Robert J. Farrauto

Robert J. Farrauto, PHD, is Professor of Practice in the Earth and Environmental Engineering Department at Columbia University in the City of New York. He retired from BASF (formerly Engelhard) as a Research Vice President after 37 years of service. He has over 40 years industrial experience in catalysis and has commercialized a number of technologies in the environmental, chemical and alternative energy fields. He holds 58 US patents and over 115 peer-reviewed journal publications. He teaches graduate and undergraduate courses focusing on catalysis. He is a co-author of Fundamentals of Industrial Catalytic Processes, 2nd Edition and Catalytic Air Pollution Control: Commercial Technology, 3rd Edition.Lucas Dorazio, PhD is a Research Chemical Engineer at BASF Corporation, Iselin, NJ where he is engaged in reforming and environmental technology. He is also Adjunct assistant professor at New Jersey Institute of Technology where he teaches environmental and industrial catalysis. Calvin H. Bartholomew, PhD is Emeritus Professor at Brigham Young University. He continues to conduct catalysis research, is active in consulting and does specialized teaching for AICHE short courses in catalysis. He has been principal investigator or co-investigator on over 60 grants and contracts and has supervised more than 175 research students. He is the author or co-author of 5 books and 120 peer-reviewed papers and reviews with emphasis on catalysis.

저자(글) Lucas Dorazio

저자(글) C. H. Bartholomew