Surfactants and Interfacial Phenomena

Milton J. Rosen 지음

Wiley 2012년 01월 20일 출간

작품소개

책소개

Now in its fourth edition, Surfactants and Interfacial Phenomena explains why and how surfactants operate in interfacial processes (such as foaming, wetting, emulsion formation and detergency), and shows the correlations between a surfactant's chemical structure and its action.Updated and revised to include more modern information, along with additional three chapters on Surfactants in Biology and Biotechnology, Nanotechnology and Surfactants, and Molecular Modeling with Surfactant Systems, this is the premier text on the properties and applications of surfactants.This book provides an easy-to-read, user-friendly resource for industrial chemists and a text for classroom use, and is an unparalleled tool for understanding and applying the latest information on surfactants. Problems are included at the end of each chapter to enhance the reader-s understanding, along with many tables of data that are not compiled elsewhere. Only the minimum mathematics is used in the explanation of topics to make it easy-to-understand and very user friendly.

목차

Preface xv1 Characteristic Features of Surfactants 1I. Conditions under which Interfacial Phenomena and Surfactants Become Significant 2II. General Structural Features and Behavior of Surfactants 2A. General Use of Charge Types 4B. General Effects of the Nature of the Hydrophobic Group 51. Length of the Hydrophobic Group 52. Branching, Unsaturation 53. Aromatic Nucleus 54. Polyoxypropylene or Polyoxyethylene (POE) Units 55. Perfluoroalkyl or Polysiloxane Group 6III. Environmental Effects of Surfactants 6A. Surfactant Biodegradability 6B. Surfactant Toxicity; Skin Irritation 7IV. Characteristic Features and Uses of Commercially Available Surfactants 8A. Anionics 91. Carboxylic Acid Salts 92. Sulfonic Acid Salts 113. Sulfuric Acid Ester Salts 154. Phosphoric and Polyphosphoric Acid Esters 175. Fluorinated Anionics 18B. Cationics 191. Long-Chain Amines and Their Salts 202. Acylated Diamines and Polyamines and Their Salts 203. Quaternary Ammonium Salts 204. Polyoxyethylenated Long-Chain Amines 225. Quaternized POE Long-Chain Amines 226. Amine Oxides 22C. Nonionics 231. Polyoxyethylenated Alkylphenols, Alkylphenol "Ethoxylates" 232. Polyoxyethylenated Straight-Chain Alcohols 243. Polyoxyethylenated Polyoxypropylene Glycols 254. Polyoxyethylenated Mercaptans 255. Long-Chain Carboxylic Acid Esters 266. Alkanolamine "Condensates," Alkanolamides 277. Tertiary Acetylenic Glycols and Their "Ethoxylates" 288. Polyoxyethylenated Silicones 289. N-Alkylpyrrolid(in)ones 2910. Alkylpolyglycosides 29D. Zwitterionics 301. pH-Sensitive Zwitterionics 302. pH-Insensitive Zwitterionics 32E. Newer Surfactants Based Upon Renewable Raw Materials 321. α-Sulfofatty Acid Methyl Esters (SME) 322. Acylated Aminoacids 333. Nopol Alkoxylates 34V. Some Useful Generalizations 34VI. Electronic Searching of the Surfactant Literature 35

출판사 서평

“Written by Milton J. Rosen and Joy T. Kunjappu, two leading authorities in the field, Surfactants and Interfacial Phenomena, Fourth Edition is an unparalleled tool for understanding and applying the latest information on surfactants, and includes unique data tables and end-of-chapter problems designed to enhance the reader&'s understanding.”& (Chimie Nouvelle, 1 March 2013)“The book is recommended to all who want to enter the interesting and yet further growing field of surfactants at interfaces.& It can serve as textbook for graduated students attending courses on surfactants and their applications. The book is also excellent for experts working in fundamental and applied research as they can find the main principles of the modification of interfaces via the impact of surfactants.”& (Tenside Surfactants Detergents, 1 May 2012)&

작가정보

저자(글) Milton J. Rosen

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Milton J. Rosen, PhD, is Professor Emeritus of Chemistry at Brooklyn College of the City University of New York. He is also the Director (ret.) of the university's Surfactant Research Institute, a pioneering organization that he founded in 1987.Joy T. Kunjappu, PhD, DSc, is a chemistry educator, consultant, and former Adjunct Professor at Columbia University and Brooklyn College. His areas of research interest include surfactant and surface science, organic chemistry, and photochemistry.