Physical and Chemical Equilibrium for Chemical Engineers

Noel de Nevers 지음

Wiley 2012년 04월 25일 출간

작품소개

책소개

This book concentrates on the topic of physical and chemical equilibrium. Using the simplest mathematics along with numerous numerical examples it accurately and rigorously covers physical and chemical equilibrium in depth and detail. It continues to cover the topics found in the first edition however numerous updates have been made including: Changes in naming and notation (the first edition used the traditional names for the Gibbs Free Energy and for Partial Molal Properties, this edition uses the more popular Gibbs Energy and Partial Molar Properties,) changes in symbols (the first edition used the Lewis-Randal fugacity rule and the popular symbol for the same quantity, this edition only uses the popular notation,) and new problems have been added to the text. Finally the second edition includes an appendix about the Bridgman table and its use.

목차

Preface xiiiAbout the Author xvNomenclature xvii1 Introduction to Equilibrium 11.1 Why Study Equilibrium?, 11.2 Stability and Equilibrium, 41.3 Time Scales and the Approach to Equilibrium, 51.4 Looking Ahead, Gibbs Energy, 51.5 Units, Conversion Factors, and Notation, 61.6 Reality and Equations, 81.7 Phases and Phase Diagrams, 81.8 The Plan of this Book, 101.9 Summary, 10References, 112 Basic Thermodynamics 132.1 Conservation and Accounting, 132.2 Conservation of Mass, 142.3 Conservation of Energy; the First Law of Thermodynamics, 152.4 The Second Law of Thermodynamics, 172.4.1 Reversibility, 172.4.2 Entropy, 182.5 Convenience Properties, 192.6 Using the First and Second Laws, 192.7 Datums and Reference States, 212.8 Measurable and Immeasurable Properties, 222.9 Work and Heat, 222.10 The Property Equation, 232.11 Equations of State (EOS), 242.11.1 EOSs Based on Theory, 252.11.2 EOSs Based on Pure Data Fitting, 252.12 Corresponding States, 262.13 Departure Functions, 282.14 The Properties of Mixtures, 282.15 The Combined First and Second Law Statement; Reversible Work, 292.16 Summary, 31References, 333 The Simplest Phase Equilibrium Examples and Some Simple Estimating Rules 353.1 Some General Statements About Equilibrium, 353.2 The Simplest Example of Phase Equilibrium, 373.2.1 A Digression, the Distinction between Vapor and Gas, 373.2.2 Back to the Simplest Equilibrium, 373.3 The Next Level of Complexity in Phase Equilibrium, 373.4 Some Simple Estimating Rules: Raoult&-s and Henry&-s &"Laws&", 393.5 The General Two-Phase Equilibrium Calculation, 433.6 Some Simple Applications of Raoult&-s and Henry&-s Laws, 433.7 The Uses and Limits of Raoult&-s and Henry&-s Laws, 463.8 Summary, 46References, 484 Minimization of Gibbs Energy 494.1 The Fundamental Thermody

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저자(글) Noel de Nevers

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NOEL de NEVERS, PhD, followed five years of working for Chevron with thirty-seven years as a Professor in the Chemical Engineering Department of the University of Utah. His textbooks (and research papers) are in fluid mechanics, thermodynamics, and air pollution control engineering. He regularly consults as an expert on explosions, fires, and toxic exposures.In addition to technical work, he has three quot;de Nevers's Lawsquot; in a Murphy's Laws compilation and won the title quot;Poet Laureate of Jell-O Saladquot; in a Salt Lake City competition, with three limericks and a quatrain. He has climbed the Grand Teton, Mt. Rainier, Mt. Whitney, Kala Pattar, and Mt. Kilimanjaro, and is the official discoverer of Private Arch in Arches National Park.