Handbook of Infrared Spectroscopy of Ultrathin Films

Valeri P. Tolstoy 지음

Wiley-VCH 2003년 07월 21일 출간

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Because of the rapid increase in commercially available Fourier transform infrared spectrometers and computers over the past ten years, it has now become feasible to use IR spectrometry to characterize very thin films at extended interfaces. At the same time, interest in thin films has grown tremendously because of applications in microelectronics, sensors, catalysis, and nanotechnology. The Handbook of Infrared Spectroscopy of Ultrathin Films provides a practical guide to experimental methods, up-to-date theory, and considerable reference data, critical for scientists who want to measure and interpret IR spectra of ultrathin films. This authoritative volume also: Offers information needed to effectively apply IR spectroscopy to the analysis and evaluation of thin and ultrathin films on flat and rough surfaces and on powders at solid-gaseous, solid-liquid, liquid-gaseous, liquid-liquid, and solid-solid interfaces.Provides full discussion of theory underlying techniquesDescribes experimental methods in detail, including optimum conditions for recording spectra and the interpretation of spectraGives detailed information on equipment, accessories, and techniquesProvides IR spectroscopic data tables as appendixes, including the first compilation of published data on longitudinal frequencies of different substancesCovers new approaches, such as Surface Enhanced IR spectroscopy (SEIR), time-resolved FTIR spectroscopy, high-resolution microspectroscopy and using synchotron radiation

목차

Preface.Acronyms and Symbols.Introduction.1. Absorption and Reflection of Infrared Radiation by.Ultrathin Films.1.1. Macroscopic Theory of Propagation of Electromagnetic.Waves in Infinite Medium.1.2. Modeling Optical Properties of a Material.1.3. Classical Dispersion Models of Absorption.1.4. Propagation of IR Radiation through Planar Interface between Two Isotropic Media.1.4.1. Transparent Media.1.4.2. General Case.1.5. Reflection of Radiation at Planar Interface Covered by Single Layer1.6. Transmission of Layer Located at Interface between Two Isotropic Semi-infinite Media.1.7. System of Plane&~Parallel Layers: Matrix Method.1.8. Energy Absorption in Layered Media.1.8.1. External Reflection: Transparent Substrates.1.8.2. External Reflection: Metallic Substrates.1.8.3. ATR.1.9. Effective Medium Theory.1.10. Diffuse Reflection and Transmission.Appendix.References.2. Optimum Conditions for Recording Infrared Spectra of Ultrathin Films.2.1. IR Transmission Spectra Obtained in Polarized Radiation.2.2. IRRAS Spectra of Layers on Metallic Surfaces (&"Metallic&" IRRAS).2.3. IRRAS of Layers on Semiconductors and Dielectrics.2.3.1. Transparent and Weakly Absorbing Substrates (&"Transparent&" IRRAS).2.3.2. Absorbing Substrates.2.3.3. Buried Metal Layer Substrates (BML-IRRAS).2.4. ATR Spectra.2.5. IR Spectra of Layers Located at Interface.2.5.1. Transmission.2.5.2. Metallic IRRAS.2.5.3. Transparent IRRAS.2.5.4. ATR.2.6. Choosing Appropriate IR Spectroscopic Method for Layer on Flat Surface.2.7. Coatings on Powders, Fibers, and Matte Surfaces.2.7.1. Transmission.2.7.2. Diffuse Transmittance and Diffuse Reflectance.2.7.3. ATR.2.7.4. Comparison of IR Spectroscopic Methods for Studying Ultrathin Films on Powders.References.3. Interpretation of IR Spectra of Ultrathin Films.3.1. Dependence of Transmission, ATR,

출판사 서평

"…Wiley InterScience, the publisher of many state-of-the-art science books, has enlarged our understanding of infrared (IR) spectroscopy significantly with this book." (Journal of Metals Online, March 31, 2005)&"...interesting& for the polymer community...due to the wide range of subjects...and also for the completeness...&" (Polymer News, Vol. 28, No. 11)

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저자(글) Valeri P. Tolstoy

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VALERI P. TOLSTOY, PhD, is Professor in the Department of Solid State Chemistry at St. Petersburg State University.IRINA V. CHERNYSHOVA, PhD, is Professor in the Physics Department at St. Petersburg State Technical University.VALERI A. SKRYSHEVSKY, PhD, is Professor in the Radiophysics Department at National Shevchenko University.